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Record W4382813600 · doi:10.1515/gps-2022-8128

Novel <i>in situ</i> synthesis of quaternary core–shell metallic sulfide nanocomposites for degradation of organic dyes and hydrogen production

2023· article· en· W4382813600 on OpenAlexaff
Yousaf Khan, Uzma Sharafat, Saima Gul, Mohammad Iqbal Khan, Muhammad Ismail, Murad Ali Khan, Rafia Younus, Sher Bahadar Khan

Bibliographic record

VenueGreen Processing and Synthesis · 2023
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsPhotocatalysisNanocompositeFourier transform infrared spectroscopyNanomaterialsMaterials scienceCatalysisNanomaterial-based catalystChemical engineeringEnvironmental pollutionCongo redHydrogen productionChemistryAdsorptionNanotechnologyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Environmental remediation of toxic organic pollutants on catalytic degradation has gained much attention. Organic dyes and fossil fuels as pollutants are the two major problems nowadays. The efficient and targeted eradication of organic dye from water systems is a critical global concern for the treatment of both drinking water and wastewater. In this study, ZnO–ZnS–CdO–CdS quaternary core–shell nanocomposites (NCs) were synthesized using Ricinus communis as a stabilizing agent and hydrazine hydrate as a reducing agent. UV-visible spectroscopy and photoluminescence confirmed the formation of NCs. Fourier transform infrared spectroscopy confirmed the presence of functional groups, while scanning electron microscopy analysis revealed that the morphology of nanomaterials was spherical and poly distributed. X-ray powder diffraction confirmed the crystalline nature of prepared samples. The prepared nanocatalysts were used in the production of hydrogen gas from green sources of the Brassica campestris leaf extract and the degradation of Congo red and methyl red dyes. Overall, the photocatalytic performance of NCs and their design was successful. The prepared catalysts were not only active in the degradation of a single substrate but also in the degradation of a mixture of dyes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.086
Threshold uncertainty score0.685

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.263
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2023
Admission routes1
Has abstractyes

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