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Record W4383047381 · doi:10.5194/acp-23-7241-2023

High sulfur dioxide deposition velocities measured with the flux–gradient technique in a boreal forest in the Alberta Oil Sands Region

2023· article· en· W4383047381 on OpenAlexafffundabout
Mark Gordon, Dane Blanchard, Timothy Jiang, Paul A. Makar, Ralf M. Staebler, Julian Aherne, C. Mihele, Xuan‐Yi Zhang

Bibliographic record

VenueAtmospheric chemistry and physics · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsUniversity of GuelphTrent UniversityEnvironment and Climate Change CanadaYork University
FundersEnvironment and Climate Change Canada
KeywordsDeposition (geology)Flux (metallurgy)Environmental scienceTaigaAtmospheric sciencesBorealRange (aeronautics)Atmosphere (unit)Oil sandsWind speedSulfur dioxideMeteorologyGeologyChemistryGeographyForestryMaterials scienceGeomorphology

Abstract

fetched live from OpenAlex

The emission of SO 2 from the Athabasca Oil Sands Region (AOSR) has been shown to impact the surrounding forest area. Recent studies using aircraft-based measurements have demonstrated that deposition of SO 2 to the forest is at a rate many times higher than model estimates. Here we use the flux–gradient method to estimate SO 2 deposition rates at two tower sites in the boreal forest downwind of AOSR SO 2 emissions. We use both continuous and passive sampler measurements and compare the two techniques. The measurements infer SO 2 deposition velocities ranging from 2.1–5.9 cm s −1 (when corrections are applied). There are uncertainties associated with the passive sampler flux–gradient analysis, primarily due to an assumed Schmidt number, a required assumption of independent variables, and potential wind effects. We estimate the total uncertainty as ± 2 cm s −1 . Accounting for these uncertainties, the range of measurements is approximately double the previous aircraft-based measurements (1.2–3.4 cm s −1 ) and more than 10 times higher than model estimates for the same measurement periods (0.1–0.6 cm s −1 ), suggesting that SO 2 in the AOSR has a much shorter lifetime in the atmosphere than is currently predicted by models.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.153
Threshold uncertainty score0.308

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.182
Teacher spread0.174 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2023
Admission routes3
Has abstractyes

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