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Record W4383223464 · doi:10.1139/cjes-2023-0019

Origin of gases and waters from a hypersaline, carbonate spring on Anticosti Island, Québec, Canada

2023· article· en· W4383223464 on OpenAlexaffvenueabout
Pascale Daoust, Ian D. Clark, André Desrochers

Bibliographic record

VenueCanadian Journal of Earth Sciences · 2023
Typearticle
Languageen
FieldEnvironmental Science
TopicMethane Hydrates and Related Phenomena
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsGeologyCalciteMeteoric waterGeochemistryCarbonateHaliteOrdovicianSeawaterAragoniteMineralogyOceanographyPaleontologyStructural basinChemistry

Abstract

fetched live from OpenAlex

Hypersaline spring water (TDS ∼ 85 g/L) and gas are escaping from the top of a calcite travertine mound on Anticosti Island. This mound is located in the Chaloupe River area above the Jupiter Fault which cuts through the Ordovician formations in the subsurface, including the oil and gas-rich Macasty Shale Formation. The Cl content is approximately 3 times that of seawater, but the geochemical profile indicates it to be a Paleozoic basin brine (geogenic He = 2E–7 cc/cc) evaporatively enriched beyond halite saturation (Br:Cl molar ratio = 0.0022 ± 0.00013) that has been diluted by some 73 ± 6% with meteoric waters. Measurable tritium (3.4 TU) indicates this to be a mixture of modern and Holocene recharge. The radioiodine (129I < 10 million atoms/L) is a three-component mixture of geogenic and post-nuclear contributions with low levels in pre-nuclear Holocene recharge. Degassing at the vent (1% to 2% CO2, PCO2 = 0.02 atm, >90% CH4) provokes calcite precipitation and travertine mound formation. Methane comprises a thermo-catalytic component and a biogenic component produced at depth in the organic-rich Macasty Formation by reduction of surface-derived dissolved inorganic carbon (DIC; a14C = 3.5 pMC), producing enriched δ13CDIC values recorded in the travertine. The occurrence of basin-derived brine and gas discharging in association with the surface expression of the Jupiter fault implies that this fault provides a pathway for deep circulation of meteoric waters, likely driven by the relief on the island.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score0.220

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.002
Science and technology studies0.0030.001
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0070.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.202
Teacher spread0.187 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes3
Has abstractyes

Explore more

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