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Record W4384661994 · doi:10.22215/etd/2023-15631

Oxidation Study of Incoloy 800H Tubes Exposed to Super-Heated Steam and Supercritical Water

2023· dissertation· en· W4384661994 on OpenAlexaffabout
Qays Nazarali

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldEngineering
TopicSubcritical and Supercritical Water Processes
Canadian institutionsCarleton University
Fundersnot available
KeywordsIncoloySupercritical fluidMaterials scienceOxideScanning electron microscopeMetallurgySpallationAustenitic stainless steelStress corrosion crackingCladding (metalworking)CorrosionComposite materialChemistryNeutron

Abstract

fetched live from OpenAlex

Incoloy 800H, a high-nickel austenitic alloy, has great merit for use in Supercritical Water (SCW). The development of the CANada Deuterium Uranium (CANDU) nuclear Supercritical Water Reactor (SCWR) was the driving force behind this research to investigate the oxidation performance of Incoloy 800H for use as fuel cladding. The oxidation behaviour of Incoloy 800H was investigated in Super-Heated Steam (SHS) and in SCW using novel tube specimens. Four specimen configurations were prepared to have a combination of Open-Ends (OE) or Closed-Ends (CE) with either a Bare Surface (BS) or a NiCrAlY Coated Surface (CS). The OE and CE specimens experienced different through-thickness stress distributions due to their testing environment, which allowed comparison and characterization of their performance with regard to oxidation and stress. Standard mass and dimension change measurements performed on the test specimens were observed to be unreliable for characterizing the relative oxidation between different test environments and specimen configurations. Detailed metallographic studies were made with the aid of optical microscopy, Scanning Electron Microscopy (SEM), Energy Dispersion Spectrometry (EDS), and X-Ray Diffraction (XRD), in addition to mass and dimensional measurements. Finite Element Analysis (FEA) was performed to determine the effect that specimen configuration and testing environment have on the stress distributions within the specimens. Testing showed that BS specimens in SHS and SCW produced sufficiently similar oxidation behaviours and oxide scales; spallation of the outer Fe-rich oxide layer was believed to have occurred. The CS specimens formed a thin and discontinuous oxide under both SHS and SCW. The CE/BS tube yielded and collapsed when exposed to SCW with cracks and ‘folds’ vulnerable to oxidation forming on the collapsed surfaces. The NiCrAlY coating provided sufficient strength to reinforce the CE/CS tube preventing its collapse in SCW conditions. From the perspective of oxidation performance, it has been determined that SHS (625oC, 0.1 MPa) is a suitable medium for investigating the oxidation behaviour of Incoloy 800H in SCW (625oC, 26.14 MPa) and would provide comparatively conservative results. The coating affords the tube additional protection from both oxidation and stress, providing the potential of extending the operating life of the Incoloy 800H tubes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.022
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.252
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes2
Has abstractyes

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