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Record W4384824123 · doi:10.1002/anie.202383061

Frontispiece: Molecular Flytraps Held Together by Platinum–Platinum Intermetallic Bonds

2023· paratext· en· W4384824123 on OpenAlexaff
Miguel A. Soto, Mohammad T. Chaudhry, Gunwant K. Matharu, Francesco Lelj, Mark J. MacLachlan

Bibliographic record

VenueAngewandte Chemie International Edition · 2023
Typeparatext
Languageen
FieldChemistry
TopicSupramolecular Chemistry and Complexes
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsPlatinumIntermetallicSupramolecular chemistryMoleculeIonChemistrySolid-stateMaterials scienceNanotechnologyCrystallographyCatalysisPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Supramolecular Chemistry. In their Communication (e202305525), Mark J. MacLachlan use a single Pt−Pt bond to glue two cyclometalated hosts together and generate a flytrap-like molecule. This compound traps inorganic ions, assembles and disassembles photochemically, and irreversibly transports guests from solution to the solid state.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.258
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0570.005

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.262
Teacher spread0.248 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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