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Record W4385448687 · doi:10.1149/2754-2726/acec59

Enhancing Sensitivity of Manganese Detection in Drinking Water Using Nanomaterial AuNPs/GP

2023· article· en· W4385448687 on OpenAlex
Kirsten Macdonald, Yu Pei, Adekunle Omoboye, Nicholas Lamothe, Yichun Shi, Kevin McEleney, Sarah Jane Payne, Zhe She

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueECS Sensors Plus · 2023
Typearticle
Languageen
FieldChemistry
TopicElectrochemical Analysis and Applications
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsChronoamperometryColloidal goldNanomaterialsDetection limitMaterials scienceManganeseNanoparticleElectrodeElectrochemistryChemistryNanotechnologyCyclic voltammetryChromatographyMetallurgy

Abstract

fetched live from OpenAlex

Manganese (Mn) was previously considered a mere aesthetic concern that causes colored water and stained surfaces; however, recent epidemiological research found that excessive exposure to Mn has neurotoxic effects on humans, especially in children. In response to the health concerns, Health Canada and the World Health Organization moved towards stricter standards on Mn to protect public health. Currently, the standard analytical methods for Mn 2+ are spectroscopic. Although they are highly sensitive, they are not cost effective or portable for high frequency analysis in the field. In this article, the sensitivity of electrochemical techniques, chronoamperometry (CA) and cathodic stripping voltammetry (CSV), are compared as well as the sensitivity of a non-modified glassy carbon screen-printed electrode (GCE SPE) vs a gold nanoparticle modified graphene (AuNPs/GP) coated GCE SPE for Mn 2+ detection and quantification. Regarding the coating of the GCE SPE, detection performed with AuNPs/GP modified GCE SPE shows a wider linear range from 0–520 μ M and an improved LOD of 0.75 μ M. Application of the sensors was tested using drinking water samples returning high recovery rates from 92.9 to 106.8% depending on material and method used for Mn 2+ detection and quantification.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.036
Threshold uncertainty score0.388

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.239
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it