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Record W4385638879 · doi:10.1038/s41561-023-01237-9

Shortwave absorption by wildfire smoke dominated by dark brown carbon

2023· article· en· W4385638879 on OpenAlex
Rajan K. Chakrabarty, Nishit Shetty, Arashdeep Singh Thind, Payton Beeler, Benjamin J. Sumlin, Chenchong Zhang, Pai Liu, Juan Carlos Idrobo, Kouji Adachi, N. L. Wagner, Joshua P. Schwarz, Adam T. Ahern, Arthur J. Sedlacek, Andrew T. Lambe, Conner Daube, Ming Lyu, Chao Liu, Scott C. Herndon, T. B. Onasch, Rohan Mishra

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueNature Geoscience · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsUniversity of Alberta
FundersClimate Program OfficeOffice of ScienceNational Oceanic and Atmospheric AdministrationMontana State UniversityNuclear Safety and Security CommissionOak Ridge National LaboratoryBiological and Environmental ResearchNational Natural Science Foundation of ChinaU.S. Department of CommerceJapan Society for the Promotion of Science LondonUT-BattelleLaboratory Directed Research and DevelopmentBattelleNational Aeronautics and Space AdministrationU.S. Department of EnergyNational Science Foundation
KeywordsShortwave radiationAtmospheric sciencesEnvironmental scienceShortwaveAtmosphere (unit)Radiative forcingAbsorption (acoustics)Carbon fibersAerosolCarbon blackExtinction (optical mineralogy)Radiative transferCarbon sinkClimatologyClimate changeRadiationChemistryMeteorologyPhysicsMaterials scienceEcologyMineralogy

Abstract

fetched live from OpenAlex

Wildfires emit large amounts of black carbon and light-absorbing organic carbon, known as brown carbon, into the atmosphere. These particles perturb Earth's radiation budget through absorption of incoming shortwave radiation. It is generally thought that brown carbon loses its absorptivity after emission in the atmosphere due to sunlight-driven photochemical bleaching. Consequently, the atmospheric warming effect exerted by brown carbon remains highly variable and poorly represented in climate models compared with that of the relatively nonreactive black carbon. Given that wildfires are predicted to increase globally in the coming decades, it is increasingly important to quantify these radiative impacts. Here we present measurements of ensemble-scale and particle-scale shortwave absorption in smoke plumes from wildfires in the western United States. We find that a type of dark brown carbon contributes three-quarters of the short visible light absorption and half of the long visible light absorption. This strongly absorbing organic aerosol species is water insoluble, resists daytime photobleaching and increases in absorptivity with night-time atmospheric processing. Our findings suggest that parameterizations of brown carbon in climate models need to be revised to improve the estimation of smoke aerosol radiative forcing and associated warming.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.169
Threshold uncertainty score0.623

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.214
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it