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Record W4385857436 · doi:10.1021/acs.chemmater.3c01564

Comparative Electronic Structures of the Chiral Helimagnets Cr<sub>1/3</sub>NbS<sub>2</sub> and Cr<sub>1/3</sub>TaS<sub>2</sub>

2023· article· en· W4385857436 on OpenAlexafffund
Lilia S. Xie, Oscar González, Kejun Li, Matteo Michiardi, Sergey Gorovikov, Sae Hee Ryu, Shannon S. Fender, Marta Zonno, Na Hyun Jo, Sergey Zhdanovich, Chris Jozwiak, Aaron Bostwick, Samra Husremović, Matthew P. Erodici, Cameron Mollazadeh, A. Damascelli, Eli Rotenberg, Yuan Ping, D. Kwabena Bediako

Bibliographic record

VenueChemistry of Materials · 2023
Typearticle
Languageen
FieldPhysics and Astronomy
TopicMagnetic properties of thin films
Canadian institutionsCanadian Light Source (Canada)University of British Columbia
FundersAir Force Office of Scientific ResearchOffice of Advanced CyberinfrastructureDivision of Graduate EducationDivision of Materials ResearchMitacsOffice of Naval ResearchBlavatnik Family FoundationCanada First Research Excellence FundMax-Planck-GesellschaftW. M. Keck Foundation3M FoundationNatural Sciences and Engineering Research Council of CanadaBrookhaven National LaboratoryCanadian Light SourceCanadian Institute for Advanced ResearchArnold and Mabel Beckman FoundationL'Oreal USAOffice of ScienceUniversity of TokyoGordon and Betty Moore FoundationUniversity of British ColumbiaU.S. Department of EnergyNational GEM ConsortiumCanadian Institutes of Health ResearchNational Science Foundation
KeywordsFerromagnetismCondensed matter physicsSpintronicsElectronic structurePhase diagramLattice (music)Photoemission spectroscopyDensity functional theoryFermi levelPhysicsCoupling (piping)Materials sciencePhase (matter)X-ray photoelectron spectroscopyNuclear magnetic resonanceElectronQuantum mechanics

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Magnetic materials with noncollinear spin textures are promising for spintronic applications. To realize practical devices, control over the length and energy scales of such spin textures is imperative. The chiral helimagnets Cr 1/3 NbS 2 and Cr 1/3 TaS 2 exhibit analogous magnetic-phase diagrams with different real-space periodicities and field dependence, positioning them as model systems for studying the relative strengths of the microscopic mechanisms giving rise to exotic spin textures. Although the electronic structure of the Nb analogue has been experimentally investigated, the Ta analogue has received far less attention. Here, we present a comprehensive suite of electronic structure studies on both Cr 1/3 NbS 2 and Cr 1/3 TaS 2 using angle-resolved photoemission spectroscopy and density functional theory. We show that bands in Cr 1/3 TaS 2 are more dispersive than their counterparts in Cr 1/3 NbS 2, resulting in markedly different Fermi wavevectors. The fact that their qualitative magnetic phase diagrams are nevertheless identical shows that hybridization between the intercalant and host lattice mediates the magnetic exchange interactions in both of these materials. We ultimately find that ferromagnetic coupling is stronger in Cr 1/3 TaS 2, but larger spin–orbit coupling (and a stronger Dzyaloshinskii–Moriya interaction) from the heavier host lattice ultimately gives rise to shorter spin textures.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.218
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2023
Admission routes2
Has abstractyes

Explore more

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