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Chemistry contribution to stratospheric ozone depletion after the unprecedented water rich Hunga Tonga eruption

2023· preprint· en· W4385899232 on OpenAlexafffund
Jun Zhang, Douglas E. Kinnison, Yunqian Zhu, Xinyue Wang, Simone Tilmes, Kimberlee Dubé, William J. Randel

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of Saskatchewan
FundersCanadian Space AgencyNational Aeronautics and Space AdministrationNational Oceanic and Atmospheric AdministrationNational Science FoundationSwedish National Space AgencyNational Center for Atmospheric Research
KeywordsOzone depletionOzoneSulfate aerosolAtmospheric sciencesStratospherePlumeClimatologyVolcanoAerosolAtmospheric chemistryNOxOzone layerWater vaporSulfateNorthern HemisphereMiddle latitudesChemistrySouthern HemisphereMeteorologyGeologyGeographyCombustion

Abstract

fetched live from OpenAlex

Following the Hunga Tonga–Hunga Ha’apai (HTHH) eruption in January 2022, stratospheric ozone depletion was observed in the Southern Hemisphere mid-latitudes and Antarctica during the 2022 austral wintertime and springtime. This eruption injected sulfur dioxide and unprecedented amounts of water vapor into the stratosphere. This work examines and quantifies the chemistry contribution of the volcanic materials to the ozone depletion using chemistry-climate model simulations with nudged meteorology. Simulated 2022 ozone and nitrogen oxides (NOx) anomalies show a good agreement with satellite observations. We find that chemistry only contributes up to 6% and 20% ozone destruction at mid-latitudes wintertime and Antarctic springtime respectively. The majority of the ozone depletion is attributed to the internal variability and dynamical changes forced by the eruption. Both the simulation and observations show a significant NOx reduction associated with the HTHH aerosol plume, indicating the enhanced dinitrogen pentoxide hydrolysis on sulfate aerosol.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.062
Threshold uncertainty score0.123

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.230
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2023
Admission routes2
Has abstractyes

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