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Record W4385984935 · doi:10.26434/chemrxiv-2023-d3ksb

An Atlas of the base inter-RNA stacks involved in bacterial translation

2023· preprint· en· W4385984935 on OpenAlexafffund
Zakir Ali, Teagan Kukhta, John F. Trant, Purshotam Sharma

Bibliographic record

VenueChemRxiv · 2023
Typepreprint
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicRNA and protein synthesis mechanisms
Canadian institutionsUniversity of Windsor
FundersNatural Sciences and Engineering Research Council of CanadaCompute Canada
KeywordsStackingRNATransfer RNARibosomal RNA23S ribosomal RNARibosomeBiologyBase pairTranslation (biology)Nucleic acid structureMessenger RNAGeneticsCrystallographyComputational biologyChemistryGene

Abstract

fetched live from OpenAlex

Nucleobase-specific noncovalent interactions (i.e., inter-RNA base pairing and stacking) play a crucial role in the RNA-driven biochemical process of translation. Although the structural details of translation are well studied, especially base-pairing, the role of nucleobase-specific inter-RNA stacking interactions is still not fully appreciated. Herein, we provide a comprehensive analysis of the stacking interactions between different RNA components in the available crystal structures of the bacterial ribosome caught at different stages of translation. Analysis of tRNA||rRNA stacking interactions reveals distinct stacking behaviour; both the A-and E-site tRNAs exhibit unique stacking patterns with 23S rRNA bases, while P-site tRNAs stack with 16S rRNA bases. Furthermore, E-site stacks exhibit diverse face orientations and ring topologies―rare for inter-chain RNA interactions―with higher average interaction energies than found in either A or P-site rRNA||tRNA stacks. This suggests that stacking may be essential for stabilizing tRNA progression to and through the E-site. Additionally, examination of mRNA||rRNA stacking interactions reveals other stacking geometries, which depend on the site of tRNA binding; A-site mRNA||rRNA stacks exhibit more frequent interactions with high stability, suggesting they play an essential role in mRNA positioning within the translational complex. Similarly, analysis of 16S rRNA||23S rRNA stacks highlights the importance of specific bases in maintaining the integrity of the translational complex by linking the two rRNAs. Furthermore, tRNA||mRNA stacking interactions exhibit distinct geometries and energetics at the E-site, indicating their significance during tRNA translocation and elimination. Overall, the analysis demonstrates that both A and E-sites display a broader and more diverse distribution of inter-RNA stacking interactions compared to the P-site. Notably, P-site stacking interactions are the least stable, suggesting their diminished role due to the need for interactions to be dominated by codon:anticodon base pairing to avoid misreading the mRNA. Stacking interactions in the active ribosome are not simply accidental byproducts of biochemistry but are invoked to compensate and support the integrity and dynamics of translation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.021

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0020.003
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0000.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0060.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.267
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2023
Admission routes2
Has abstractyes

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