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Record W4386026131 · doi:10.1021/acsapm.3c01360

Hard Epoxy Coating with Lasting Low Ice Adhesion Strength

2023· article· en· W4386026131 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Applied Polymer Materials · 2023
Typearticle
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceCoatingComposite materialEpoxyBilayerSiliconeSurface roughnessSilicone oilPolymerChemical engineeringMembrane

Abstract

fetched live from OpenAlex

A high-hardness ( H ) coating typically has an elevated ice adhesion strength (τ), while a soft coating tends to shed ice easily. We recently reported a one-step process for a bilayer polyurethane coating that achieved both high H and low τ, effectively decoupling H from τ. However, these low τ values remained stable only through 12 icing/deicing cycles, beyond which τ rapidly increased. To maintain consistently low τ, another bilayer coating is prepared using a diamine, an epoxy compound, and poly(glycidyl methacrylate) with poly(dimethylsiloxane) (PDMS) side chains. This coating features a bulk hardness of 0.31 ± 0.03 GPa, PDMS nanopools in the matrix, and a liquid-like PDMS brush layer on the surface. A silicone oil mixture (SO m ) can be added to the formulation before coating formation. Increasing the SO m content enlarges PDMS/SO m nanopools and surface roughness. Lubricated coatings are produced by applying SO m or individual silicone oils (SOs) of varying viscosities to preformed nonporous and microporous coatings. This study compares ice-shedding properties of these coatings over 30 icing/deicing cycles. Results show that the smooth bilayer epoxy coating, lubricated with 1.55 g/m 2 SO m, maintains τ values <5 kPa, 100 times lower than glass, after 30 icing/deicing cycles. This marks the first polymer coating to simultaneously exhibit high H alongside such consistently low τ values over numerous icing/deicing cycles.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.238
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it