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Record W4386691726 · doi:10.1039/d3dt02596a

Peripheral site modification in a family of dinuclear [Dy<sub>2</sub>(hynad)<sub>2–6</sub>(NO<sub>3</sub>)<sub>0–6</sub>(sol)<sub>0–2</sub>]<sup>0/2−</sup> single-molecule magnets bearing a {Dy<sub>2</sub>(μ-OR)<sub>2</sub>}<sup>4+</sup> diamond-shaped core and exhibiting dissimilar magnetic dynamics

2023· article· en· W4386691726 on OpenAlexaff
Alexandros S. Armenis, Dimitris I. Alexandropoulos, Anne Worrell, Luı́s Cunha-Silva, Kim R. Dunbar, Theocharis C. Stamatatos

Bibliographic record

VenueDalton Transactions · 2023
Typearticle
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsBrock University
FundersLaboratório Associado para a Química VerdeRede de Química e TecnologiaFundação para a Ciência e a TecnologiaMinistério da Ciência, Tecnologia e Ensino Superior
KeywordsCrystallographyMaterials scienceChemistry

Abstract

fetched live from OpenAlex

A new family of four dinuclear Dy III complexes bearing the same {Dy 2 (μ-OR) 2 } 4+ core but different peripheral ligands has been isolated; all complexes exhibit slow relaxation of their magnetization and SMM properties.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.004
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.241
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0040.001
Meta-epidemiology (narrow)0.0050.006
Meta-epidemiology (broad)0.0050.002
Bibliometrics0.0040.008
Science and technology studies0.0040.003
Scholarly communication0.0020.004
Open science0.0030.001
Research integrity0.0030.004
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.243
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2023
Admission routes1
Has abstractyes

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