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Record W4386855270 · doi:10.1149/ma2023-0191161mtgabs

Effect of Device Design Parameters on the Sensitivity of Graphene Field-Effect Transistors

2023· article· en· W4386855270 on OpenAlexaff
Ryan Borotra, Claudia M. Bazán, Delphine Bouilly

Bibliographic record

VenueECS Meeting Abstracts · 2023
Typearticle
Languageen
FieldChemical Engineering
TopicAnalytical Chemistry and Sensors
Canadian institutionsUniversité de Montréal
Fundersnot available
KeywordsGrapheneSensitivity (control systems)Materials scienceCalibration curveElectrodeOptoelectronicsTransistorCalibrationBiosensorNanotechnologyPassivationField-effect transistorAnalytical Chemistry (journal)VoltageDetection limitChemistryElectronic engineeringElectrical engineeringPhysicsChromatography

Abstract

fetched live from OpenAlex

Graphene field-effect transistors (GFETs) present several advantages for biomolecular sensing applications. Their high conductivity, carbon chemistry and sensitivity to the electrostatic environment have made GFETs a promising technology for the detection of biomarkers with high sensitivity. While research has mostly focused on biomolecular immobilization strategies to improve detection in GFET biosensors, much less attention has been given to the effect of different design parameters of the devices themselves on the sensitivity of the sensors. Here, we assess the sensitivity metrics of GFET sensors using their response to changes in buffer salinity. To do this, we incubated GFET devices in phosphate buffer solutions (PBS) with concentrations ranging from 0.001X to 10X, and collected electrical transfer curves before/after each incubation to extract the voltage of the charge neutrality point (VCNP). Two metrics were extracted from the calibration curve of VCNP against concentration: (1) the dynamic range, as the range of concentrations showing a variation of the VCNP, and (2) the sensitivity, as the slope of the calibration curve in the dynamic range, measured in mV/decade. Using small-area non-passivated GFET devices, we obtained a sensitivity of -50 mV/decade from 0.1X to 10X PBS using an Ag/AgCl reference electrode and -160 mV/decade from 0.1X to 10X PBS using a coplanar Au electrode. We will discuss the response to changes in salinity using different combinations of design parameters, including the size of the graphene area, the choice of reference electrode and the type of passivation. Overall, this study will shed light on device design optimization for increased sensitivity, giving us an indication as to which parameter combination is best for the development of highly sensitive biosensors.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.005
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.005
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0020.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.249
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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