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Record W4387103391 · doi:10.1002/eem2.12672

Electrochemical Activation‐Induced Structural Transformation in Ni(<scp>OH</scp>)<sub>2</sub>/<scp>Ti<sub>3</sub>C<sub>2</sub>T</scp><i><sub>x</sub></i>/<scp>NF</scp> Systems with Enhanced Electrochemical Performance for Hybrid Supercapacitors

2023· article· en· W4387103391 on OpenAlexaff
Chuming Xu, Lu Dai, Yiming Zhao, Shuang Li, Ya‐Pan Wu, Xue‐Qian Wu, Gaixia Zhang, Shuhui Sun, Dong‐Sheng Li

Bibliographic record

VenueEnergy & environment materials · 2023
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsInstitut National de la Recherche ScientifiqueÉcole de Technologie Supérieure
FundersHigher Education Discipline Innovation ProjectNational Natural Science Foundation of ChinaNatural Science Foundation of Hubei ProvinceNational Science Foundation
KeywordsAnodeElectrochemistryMaterials scienceSupercapacitorCrystallinityComposite numberElectrodeCathodeChemical engineeringNickelActivated carbonBattery (electricity)NanotechnologyComposite materialChemistryMetallurgy

Abstract

fetched live from OpenAlex

Exploring a novel strategy for large‐scale production of battery‐type Ni(OH) 2 ‐based composites, with excellent capacitive performance, is still greatly challenging. Herein, we developed a facile and cost‐effective strategy to in situ grow a layer of Ni(OH) 2 /Ti 3 C 2 T x composite on the nickel foam (NF) collector, where Ti 3 C 2 T x is not only a conductive component, but also a catalyst that accelerates the oxidation of NF to Ni(OH) 2 . Detailed analysis reveals that the crystallinity, morphology, and electronic structure of the integrated electrode can be tuned via the electrochemical activation, which is beneficial for improving electrical conductivity and redox activity. As expected, the integrated electrode shows a specific capacity of 1.09 C cm −2 at 1 mA cm −2 after three custom activation cycles and maintains 92.4% of the initial capacity after 1500 cycles. Moreover, a hybrid supercapacitor composed of Ni(OH) 2 /Ti 3 C 2 T x /NF cathode and activated carbon anode provides an energy density of 0.1 mWh cm −2 at a power density of 0.97 mW cm −2 , and excellent cycling stability with about 110% capacity retention rate after 5000 cycles. This work would afford an economical and convenient method to steer commercial Ni foam into advanced Ni(OH) 2 ‐based composite materials as binder‐free electrodes for hybrid supercapacitors.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0010.003
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.190
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2023
Admission routes1
Has abstractyes

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