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Record W4387114371 · doi:10.1002/smll.202305136

Fabrication of Multi‐Layered Paper‐Based Supercapacitor Anode by Growing Cu(OH)<sub>2</sub> Nanorods on Oxygen Functional Groups‐Rich Sponge‐Like Carbon Fibers

2023· article· en· W4387114371 on OpenAlexafffund
Guoliang Zhang, Yaoyao Li, Ruifeng Zhu, Zhe Wei Huang, Dan Zhang, Zhu Long, Yuning Li

Bibliographic record

VenueSmall · 2023
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsUniversity of Waterloo
FundersChina Scholarship CouncilNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of China
KeywordsSupercapacitorMaterials scienceAnodeCapacitanceCathodeElectrolyteChemical engineeringNanorodCarbon fibersElectrodeFabricationCurrent densityEnergy storageNanotechnologyFiberGraphiteComposite materialComposite numberChemistry

Abstract

fetched live from OpenAlex

Abstract This work addresses the challenges in developing carbon fiber paper‐based supercapacitors (SCs) with high energy density by focusing on the limited capacity of carbon fiber. To overcome this limitation, a sponge‐like porous carbon fiber paper enriched with oxygen functional groups (OFGs) is prepared, and Cu(OH)2 nanorods are grown on its surface to construct the SC anode. This design results in a multi‐layered carbon fiber paper‐based electrode with a specific structure and enhanced capacitance. The Cu(OH)2@PCFP anode exhibits an areal capacitance of 547.83 mF cm−2 at a current density of 1 mA cm−2 and demonstrates excellent capacitance retention of 99.8% after 10 000 cycles. Theoretical calculations further confirm that the Cu(OH)2/OFGs‐graphite heterostructure exhibits higher conductivity, facilitating faster charge transfer. A solid‐state SC is successfully assembled using Ketjen Black@PCFP as the cathode and KOH/PVA as the gel electrolyte. The resulting device exhibits an energy density of 0.21 Wh cm−2 at 1.50 mW cm−2, surpassing the performance of reported Cu(OH)2 SCs. This approach, combining materials design with an understanding of underlying mechanisms, not only expands the range of electrode materials but also provides valuable insights for the development of high‐capacity energy storage devices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.222
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2023
Admission routes2
Has abstractyes

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