Functional silicone oils and elastomers: new routes lead to new properties
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
, aminosilicones, softening of fabrics; silicone polyethers, superwetting agricultural adjuvants). However, relatively little organic chemistry is practiced in commercial silicones, limiting the types of desirable functionality that can be attained. We report the utilization of a series of simple-to-practice organic reactions that take place efficiently on silicone oils to allow the preparation of a wide variety of functional silicones. The silicone oil starting materials typically act as both solvent and educt to allow many of the newer reactions, such as Click processes, to be used to tune the properties of both silicone oil and elastomer products. The review considers the concept of 'functionality' to include: the reactive groups used to enable synthesis of more complicated structures; and separately, the functional properties of the product silicones. One such property that is considered throughout is degradability at end-of-life, which is related to the sustainability of silicones.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it