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Record W4387648920 · doi:10.1149/1945-7111/aceab2

Editors’ Choice—AutoEIS: Automated Bayesian Model Selection and Analysis for Electrochemical Impedance Spectroscopy

2023· article· en· W4387648920 on OpenAlexafffund
Runze Zhang, Robert Black, Debashish Sur, Parisa Karimi, Kangming Li, Brian DeCost, John R. Scully, Jason Hattrick‐Simpers

Bibliographic record

VenueJournal of The Electrochemical Society · 2023
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsVector InstituteNational Research Council CanadaUniversity of Toronto
FundersOffice of Naval Research GlobalOffice of Naval ResearchNational Research Council CanadaMultidisciplinary University Research InitiativeMaterials Research Science and Engineering Center, Harvard UniversityUniversity of TorontoCanada First Research Excellence FundNational Science Foundation
KeywordsDielectric spectroscopyComputer scienceGeneralizability theoryElectrocatalystElectrochemistryChemistryElectrode

Abstract

fetched live from OpenAlex

Electrochemical Impedance Spectroscopy (EIS) is a powerful tool for electrochemical analysis; however, its data can be challenging to interpret. Here, we introduce a new open-source tool named AutoEIS that assists EIS analysis by automatically proposing statistically plausible equivalent circuit models (ECMs). AutoEIS does this without requiring an exhaustive mechanistic understanding of the electrochemical systems. We demonstrate the generalizability of AutoEIS by using it to analyze EIS datasets from three distinct electrochemical systems, including thin-film oxygen evolution reaction (OER) electrocatalysis, corrosion of self-healing multi-principal components alloys, and a carbon dioxide reduction electrolyzer device. In each case, AutoEIS identified competitive or in some cases superior ECMs to those recommended by experts and provided statistical indicators of the preferred solution. The results demonstrated AutoEIS’s capability to facilitate EIS analysis without expert labels while diminishing user bias in a high-throughput manner. AutoEIS provides a generalized automated approach to facilitate EIS analysis spanning a broad suite of electrochemical applications with minimal prior knowledge of the system required. This tool holds great potential in improving the efficiency, accuracy, and ease of EIS analysis and thus creates an avenue to the widespread use of EIS in accelerating the development of new electrochemical materials and devices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.008
metaresearch head score (Gemma)0.084
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.191
Threshold uncertainty score0.637

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0080.084
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0030.002
Bibliometrics0.0020.001
Science and technology studies0.0010.001
Scholarly communication0.0050.004
Open science0.0040.003
Research integrity0.0050.006
Insufficient payload (model declined to judge)0.1910.082

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.233
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations28
Published2023
Admission routes2
Has abstractyes

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Same venueJournal of The Electrochemical SocietySame topicFuel Cells and Related MaterialsFrench-language works237,207