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Record W4387836967 · doi:10.5194/acp-23-13283-2023

N <sub>2</sub> O as a regression proxy for dynamical variability in stratospheric trace gas trends

2023· article· en· W4387836967 on OpenAlexafffund
Kimberlee Dubé, Susann Tegtmeier, Adam Bourassa, Daniel Zawada, Douglas A. Degenstein, Patrick E. Sheese, Kaley A. Walker, William J. Randel

Bibliographic record

VenueAtmospheric chemistry and physics · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of TorontoUniversity of Saskatchewan
FundersCanadian Space Agency
KeywordsTrace gasNorthern HemisphereStratosphereAtmospheric sciencesClimatologyEnvironmental scienceTropopauseProxy (statistics)Ozone layerTroposphereOzone depletionSouthern HemisphereOzoneMeteorologyGeographyGeology

Abstract

fetched live from OpenAlex

Trends in stratospheric trace gases like HCl, N 2 O, O 3 , and NO y show a hemispheric asymmetry over the last 2 decades, with trends having opposing signs in the Northern Hemisphere and Southern Hemisphere. Here we use N 2 O, a long-lived tracer with a tropospheric source, as a proxy for stratospheric circulation in the multiple linear regression model used to calculate stratospheric trace gas trends. This is done in an effort to isolate trends due to circulation changes from trends due to the chemical effects of ozone-depleting substances. Measurements from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) and the Optical Spectrograph and InfraRed Imager System (OSIRIS) are considered, along with model results from the Whole Atmosphere Community Climate Model (WACCM). Trends in HCl, O 3 , and NO y for 2004–2018 are examined. Using the N 2 O regression proxy, we show that observed HCl increases in the Northern Hemisphere are due to changes in the stratospheric circulation. We also show that negative O 3 trends above 30 hPa in the Northern Hemisphere can be explained by a change in the circulation but that negative ozone trends at lower levels cannot. Trends in stratospheric NO y are found to be largely consistent with trends in N 2 O.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.031
Threshold uncertainty score0.062

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.227
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2023
Admission routes2
Has abstractyes

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