New Insights into Internal Oxidation of Alloy 690 and Model Alloys in Hydrogenated Steam
Bibliographic record
Abstract
The oxidation behavior of Alloy 690 and Ni-xCr-10Fe model alloys exposed to 480°C hydrogenated steam, in the nickel metal stability region, was studied using a variety of techniques, including time-resolved scanning electron microscopy, transmission electron microscopy, time-of-flight secondary ion mass spectrometry, and electron energy loss spectroscopy. The alloy underwent internal oxidation intragranularly, resulting in the expulsion of metallic Ni nodules to the surface. A compact Cr-rich “healing” layer developed over time at the intragranular internal oxidation front near grain boundaries and significantly retards further internal oxidation. Protective external Cr-rich oxide formed at and very near the grain boundaries, hindering intergranular oxidation. In view of the fact that the protective oxide forms micrometers away from the grain boundaries, one cannot simply say that Cr diffuses up the boundary and forms an oxide that spreads laterally—internal stress relief must play a role, just as it does within the grains, only with different mechanisms at play.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".