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Record W4388490299 · doi:10.1111/ejss.13434

Oxygen isotope ratios of phosphates in the soil‐plant system: Limitations and future developments

2023· article· en· W4388490299 on OpenAlex
Christian von Sperber, Chiara Pistocchi, Markus Weiler, Federica Tamburini

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEuropean Journal of Soil Science · 2023
Typearticle
Languageen
FieldEnvironmental Science
TopicSoil and Water Nutrient Dynamics
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of CanadaGovernment of Canada
KeywordsBiogeochemical cycleEnvironmental chemistryIsotopes of oxygenEnvironmental scienceStable isotope ratioIsotopeIsotope analysisOxygen isotope ratio cycleEarth scienceSoil waterChemistryEcologySoil scienceGeologyBiology

Abstract

fetched live from OpenAlex

Abstract The oxygen isotope ratio of phosphates is a powerful tool to study phosphorus in the soil‐plant system. In the past two decades, the scientific community has made substantial progress in characterizing biogeochemical processes that lead to an alteration of oxygen isotope ratios in phosphates and in evaluating oxygen isotope ratios of phosphates in plants and soils under various environmental conditions around the globe. However, there are still uncertainties with respect to their interpretation in environmental systems. These uncertainties include the comprehensive analysis of isotope endmembers, artifacts during the chemical extractions and the phosphate purification protocols, overlapping isotope values from various processes and sources, gaps of knowledge about isotope effects of metabolic pathways, and the possibly erroneous assumption that insights from experiments under controlled laboratory conditions can be directly translated into the complex soil‐plant system. This paper provides a critical discussion of these uncertainties addressing recommendations and needs for future research and gives an outlook on recent technological advances, such as triple oxygen isotope analysis or the use of high‐resolution mass spectrometry. We conclude by suggesting that a concerted and systematic effort by scientists from a wide range of disciplines will be necessary to remove the uncertainties in the interpretation of oxygen isotope ratios in phosphates as an environmental tracer.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.062
Threshold uncertainty score0.195

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.202
Teacher spread0.184 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it