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Record W4388688705 · doi:10.1021/acsestengg.3c00384

Two Birds with One Stone: A Dual-Functional Washing Fluid for Shoreline Oil Spill Response

2023· article· en· W4388688705 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS ES&T Engineering · 2023
Typearticle
Languageen
FieldEngineering
TopicGas Sensing Nanomaterials and Sensors
Canadian institutionsMemorial University of NewfoundlandConcordia University
FundersNatural Resources CanadaNatural Sciences and Engineering Research Council of Canada
KeywordsChemistrySurface tensionChemical engineeringSinglet oxygenQuenching (fluorescence)RedoxEnvironmental chemistryPetroleumOxygenOrganic chemistryFluorescence

Abstract

fetched live from OpenAlex

The gigantic petroleum exploration and production are threatening the lives and well-being of people and other species. Pizeocatalysis is a bridge to transfer ceaseless mechanical energy to chemical energy and thus triggers redox reactions. In this study, piezoelectric MoS 2 was used as a surface-washing fluid to physically and chemically decontaminate oiled sands. The MoS 2 displayed single- and few-layer structures, which were conducive to piezocatalysis. The addition of MoS 2 could decrease the interfacial tension, thereby facilitating oil removal. The oil removal efficiency varied under different environmental conditions. Quenching experiments with different scavengers and electron paramagnetic resonance (EPR) spectra showed the existence of reactive oxygen species (ROS) including 1 O 2, • O 2 –, and • OH. It was found that shaking was a necessary initiator to trigger piezocatalysis and singlet oxygen ( 1 O 2 ) was the dominant ROS. The MoS 2 fluid exhibited good stability, maintaining high removal efficiency after five reuse cycles. Notably, results indicated that high-molecular-weight hydrocarbons were degraded into lower-molecular-weight ones, indicating the existence of chemical oxidation pathways in oil removal. This study provides a facile self-powered piezocatalytic surface-washing process by harnessing natural energy from water agitation to clean up oiled sands.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.255
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.211
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it