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Record W4388688705 · doi:10.1021/acsestengg.3c00384

Two Birds with One Stone: A Dual-Functional Washing Fluid for Shoreline Oil Spill Response

2023· article· en· W4388688705 on OpenAlexafffund
Rengyu Yue, Zhibin Ye, Baiyu Zhang, Chunjiang An, Zhaonian Qu, Shuyan Wan

Bibliographic record

VenueACS ES&T Engineering · 2023
Typearticle
Languageen
FieldEngineering
TopicGas Sensing Nanomaterials and Sensors
Canadian institutionsMemorial University of NewfoundlandConcordia University
FundersNatural Resources CanadaNatural Sciences and Engineering Research Council of Canada
KeywordsChemistrySurface tensionChemical engineeringSinglet oxygenQuenching (fluorescence)RedoxEnvironmental chemistryPetroleumOxygenOrganic chemistryFluorescence

Abstract

fetched live from OpenAlex

The gigantic petroleum exploration and production are threatening the lives and well-being of people and other species. Pizeocatalysis is a bridge to transfer ceaseless mechanical energy to chemical energy and thus triggers redox reactions. In this study, piezoelectric MoS 2 was used as a surface-washing fluid to physically and chemically decontaminate oiled sands. The MoS 2 displayed single- and few-layer structures, which were conducive to piezocatalysis. The addition of MoS 2 could decrease the interfacial tension, thereby facilitating oil removal. The oil removal efficiency varied under different environmental conditions. Quenching experiments with different scavengers and electron paramagnetic resonance (EPR) spectra showed the existence of reactive oxygen species (ROS) including 1 O 2, • O 2 –, and • OH. It was found that shaking was a necessary initiator to trigger piezocatalysis and singlet oxygen ( 1 O 2 ) was the dominant ROS. The MoS 2 fluid exhibited good stability, maintaining high removal efficiency after five reuse cycles. Notably, results indicated that high-molecular-weight hydrocarbons were degraded into lower-molecular-weight ones, indicating the existence of chemical oxidation pathways in oil removal. This study provides a facile self-powered piezocatalytic surface-washing process by harnessing natural energy from water agitation to clean up oiled sands.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.211
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2023
Admission routes2
Has abstractyes

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