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Record W4389613666 · doi:10.1002/cjce.25156

Enhanced catalytic oxidation via nano <scp> Cu <sub>0.5</sub> Mg <sub>0.5</sub> Fe <sub>2</sub> O <sub>4</sub> </scp> embedded in <scp>CNTs</scp> for adsorption–reduction of hexavalent chromium

2023· article· en· W4389613666 on OpenAlexvenueno aff
Pan Zhang, Qiuying Wu, Wei Wang, Xiushan Yang

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2023
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsnot available
FundersSichuan University
KeywordsAdsorptionCatalysisCarbon nanotubeX-ray photoelectron spectroscopyDesorptionMaterials scienceChemical engineeringChemical stateWastewaterComposite numberChemisorptionValence (chemistry)ChemistryNanotechnologyComposite materialPhysical chemistryWaste managementOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract A catalyst consisting of Cu 0.5 Mg 0.5 Fe 2 O 4 (CMF) supported on carbon nanotubes (CNTs) which exhibits great potential as an adsorbent for treating Cr(VI)‐contaminated wastewater has been successfully prepared. The ferrite possesses excellent magnetic properties, while CNTs have the advantage of a large surface area. This composite material not only prevents the aggregation of magnetic materials and enhances the exposure of active sites but also effectively solves the recycling problem of CNTs. Our results show that the adsorption capacity of Cu 0.5 Mg 0.5 Fe 2 O 4 –carbon nanotubes (CMF‐CNTs) for Cr(VI) wastewater (45.60 mg/g) is 1.49 times higher than that of Cu 0.5 Mg 0.5 Fe 2 O 4 (30.48 mg/g). Compared to a single catalyst, CMF‐CNTs not only improve the dispersibility of magnetic materials but also exhibit synergistic effects between the composite materials, enhancing the chemical adsorption capacity. After five consecutive adsorption and desorption experiments, the adsorption capacity of CMF‐CNTs remains at 88% of its initial value. Furthermore, the study of the catalyst before and after adsorption by XPS reveals that the valence state transition of Fe 3+ /Fe 2+ and Cu 2+ /Cu + plays a crucial role in the adsorption process. The results of this study demonstrate the potential of using waste materials for effective wastewater treatment and provide insights into the development of new adsorbents for pollutant removal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.198
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian Journal of Chemical Engineering→Same topicAdsorption and biosorption for pollutant removal→French-language works237,207→