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Record W4390146928 · doi:10.1016/j.enrev.2023.100065

Electrocatalytic conversion of methane: Recent progress and future prospects

2023· article· en· W4390146928 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnergy Reviews · 2023
Typearticle
Languageen
FieldEnergy
TopicCO2 Reduction Techniques and Catalysts
Canadian institutionsUniversity of Calgary
FundersKey Research and Development Program of Zhejiang Province
KeywordsMethaneElectrocatalystDehydrogenationGreenhouse gasChemistryElectrochemistryNanotechnologyCatalysisEnvironmental scienceMaterials scienceElectrodeOrganic chemistryPhysical chemistry

Abstract

fetched live from OpenAlex

Methane has gained significant attention due to its abundant reserves and notable greenhouse effect. Electrocatalytic conversion of methane is an efficient and green pathway proceeding under mild conditions. However, the low solubility of methane in aqueous electrolytes imposes mass transfer limitations, leading to low current densities in electrocatalytic reactions and hindering large-scale production. This paper discusses the recent progress in quite a few aspects of electrocatalytic conversion of methane. Firstly, the reaction mechanisms involved in methane electrocatalysis are summarized, including dehydrogenation and C–H bond cleavage mediated by the active species. Next, we discuss how to promote electrochemical methane conversion regarding both the reaction process and mass transfer from the perspective of chemical engineering. Considerable efforts have been done to enhance the reaction process, including developing efficient electrocatalyst and devices. Meanwhile, the enhancement of transport processes via, e.g. improving the solubility of methane and modification on the transport area and distance, also facilitates more efficient methane conversion. Finally, an outlook on future development challenges is provided.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Other design · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.944
Threshold uncertainty score0.462

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.274
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it