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Record W4390812425 · doi:10.1007/s12598-023-02584-7

Rare earth element‐modified MOF materials: synthesis and photocatalytic applications in environmental remediation

2024· article· en· W4390812425 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueRare Metals · 2024
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsInstitut National de la Recherche Scientifique
FundersNational Key Research and Development Program of ChinaNational Science Fund for Distinguished Young ScholarsChina Postdoctoral Science FoundationNatural Science Foundation of Inner MongoliaNatural Science Foundation of Heilongjiang ProvinceNational Natural Science Foundation of China
KeywordsPhotocatalysisMaterials scienceRare earthRare-earth elementNanotechnologyWater splittingEnvironmental remediationMetal-organic frameworkEarth (classical element)Absorption (acoustics)CatalysisChemistryPhysical chemistryMetallurgyPhysics

Abstract

fetched live from OpenAlex

Abstract Metal–organic framework‐like materials (MOFs) have been developed in the fields of photocatalysis for their excellent optical properties and physicochemical properties, including environmental remediation, CO 2 photoreduction, water splitting, and so on. With their important roles in various fields, rare earth elements have received growing interests from scientists. Modifying MOFs with rare earth elements for modification allows broadening the absorption spectrum, while the active electrons on their empty 4f orbitals can act as traps to capture photoexcited carriers to inhibit the recombination of electron–hole pairs, thus promoting photocatalytic activity. Therefore, rare earth elements modified MOFs provide an attractive way to achieve their high value utilization. In this mini‐review, the synthesis of rare earth element‐modified MOFs photocatalysts and corresponding applications in the removal of antibiotics, CO 2 reduction, and hydrogen production are constructively summarized and discussed. Finally, the latest advancements and current difficulties of these materials as well as the application prospects are also provided.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score0.995

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.238
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it