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Multiscale CO budget estimates across South America: quantifying local sources and long range transport

2024· preprint· en· W4390838019 on OpenAlexaff
Pablo Lichtig, Benjamin Gaubert, L. K. Emmons, Duseong S. Jo, Patrick Callaghan, Sérgio Ibarra-Espinosa, Laura Dawidowski, Guy Brasseur, Gabriele Pfister

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsAtomic Energy (Canada)
FundersDeutsches KlimarechenzentrumNational Science Foundation
KeywordsBiomass burningSouthern HemisphereBiomass (ecology)Environmental scienceCarbon monoxideAtmospheric sciencesTroposphereNorthern HemisphereAmazon rainforestAtmospheric chemistryRange (aeronautics)ClimatologyChemistryGeographyAerosolMeteorologyOzoneGeologyEcologyOceanography

Abstract

fetched live from OpenAlex

South America is a large continent situated mostly in the Southern Hemisphere (SH) with complex topography and diverse emissions sources. However, the atmospheric chemistry of this region has been historically understudied. Here, we employ the Multi-Scale Infrastructure for Chemistry and Aerosols, a novel global circulation model with regional refinement capabilities and full chemistry, to explore the sources and distribution of the carbon monoxide (CO) tropospheric column in South America during 2019, and also to assess the effect that South American primary emissions have over the rest of the world. Most of the CO over South America can be explained either by NMVOC secondary chemical production or by biomass burning emissions, with biomass burning as the main explanation for the variability in CO. Biomass burning in Central Africa is a relevant contributor to CO in all of the continent, including the southern tip. Biogenic emissions play a dual role in CO concentrations: they provide volatile organic compounds that contribute to the secondary CO production, but they also destroy OH, which limits the chemical production and destruction of CO. As a net effect, the lifetime of CO is extended to ~120 days on average over the Amazon, while still being in the range of 30-60 days in the rest of South America.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.090
Threshold uncertainty score0.179

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.027
GPT teacher head0.273
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes1
Has abstractyes

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