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Record W4391103084 · doi:10.1021/acssusresmgt.3c00053

Engineering Magnetic Biochar from Polyphenol-Functionalized Biomass for the Removal of Broad-Spectrum Water Contaminants

2024· article· en· W4391103084 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueACS Sustainable Resource Management · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsUniversity of British Columbia
FundersNational Key Research and Development Program of ChinaState Key Laboratory of Polymer Materials EngineeringSichuan UniversityNational Natural Science Foundation of China
KeywordsBiocharPyrolysisAdsorptionContaminationNitrogenPortable water purificationWater treatmentMetal ions in aqueous solutionEnvironmental chemistryChemistryMaterials scienceMetalEnvironmental scienceEnvironmental engineeringMetallurgyOrganic chemistry

Abstract

fetched live from OpenAlex

Various water contaminants raise concerns about potential negative effects on aquatic ecosystems and human health, which demand breakthrough technologies for the effective removal of a wide range of water contaminants. Recently, nitrogen-doped biochar has shown promise in the removal of various contaminants due to its merits of having a high surface area, versatile surface functionality, and variable surface charge. However, obtaining nitrogen-doped biochar with a high nitrogen content and large surface area simultaneously is challenging. Herein, we developed a nitrogen-rich magnetic and porous biochar (NMPC) via facile pyrolysis of polyphenol and metal ions cofunctionalized collagen. Benefiting from a large surface area (1194.4 m 2 g –1 ) and a high nitrogen content (8.35 wt %), NMPC exhibited high adsorption performance for broad-spectrum water contaminants, including dyes, antibiotics, and heavy metal ions. Besides, NMPC could be magnetically separated for easy recycling with the embedded magnetic iron carbide (Fe 3 C) and still maintained a high removal performance even in a six-cycle test. This work provides new possibilities for the fabrication of nitrogen-rich magnetic biochar which holds great potential in efficient removal of broad-spectrum water contaminants.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.917
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0040.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.195
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it