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Record W4391317271 · doi:10.1002/prep.202300199

Enhancing energy release of aluminized propellants and explosives through fluorinated binder

2024· article· en· W4391317271 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenuePropellants Explosives Pyrotechnics · 2024
Typearticle
Languageen
FieldEngineering
TopicEnergetic Materials and Combustion
Canadian institutionsMD Precision (Canada)
FundersNational Natural Science Foundation of China
KeywordsPropellantExplosive materialDetonationMaterials scienceCombustionFluorineThermal decompositionComposite materialDetonation velocityThermal stabilityChemical engineeringChemistryMetallurgyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract The use of fluorinated binders can enhance the combustion properties of Al in energetic materials. The underlying mechanism is under investigation and a rational strategy in terms of application has yet to be fully developed. In this study, we have investigated the effect of using a fluorine‐modified hydroxy‐terminated polyether (HTPE) binder to cast aluminized propellants and explosives. We have focused on the combustion behavior and energy release characteristics of Al particles with and without the fluorinated binder during propellant combustion and explosive detonation. The propellants combustion process was recorded using a high‐speed camera and an infrared thermometer. The heat of detonation, detonation velocity and thermal stability of the explosives were investigated using a constant temperature calorimeter, an electrometric method and a small‐scale thermal cook‐off test, respectively. The fluorine‐modified HTPE propellant has exhibited a higher flame temperature and greater energy release efficiency than the HTPE propellant. Moreover, the fluorine‐modified HTPE propellant is characterized by smaller particle agglomerates, leading to a reduction in the mass percentage of agglomerates from 73 wt% to 42 wt%. The detonation heat of fluorine‐modified HTPE explosive increases from 75.2 % to 81 %, but the detonation velocity decreased from 7745 m/s to 7622 m/s. In addition, the fluorine‐modified HTPE binder maintained the thermal stability of explosives due to a milder decomposition before thermal runaway.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.206
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it