Local probe investigation of the spin dynamics in the kagome and interlayers of orthorhombic barlowite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Cu</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi>OD</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn>6</mml:mn></mml:msub><mml:mi>FBr</mml:mi></mml:mrow></mml:math>: <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mmultiscripts><mml:mi>Br</mml:mi><mml:mprescripts/><mml:none/><mml:mn>79</mml:mn></mml:mmultiscripts></mml:math> and <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mmultiscripts><mml:mi>Cu</mml:mi><mml:mprescripts/><mml:none/><mml:mn>63</mml:mn></mml:mmultiscripts></mml:math> NQR study
Bibliographic record
Abstract
We report $^{79}\mathrm{Br}$ and $^{63}\mathrm{Cu}$ nuclear quadrupole resonance (NQR) in the paramagnetic state above ${T}_{\text{N}}=15$ K of the antiferromagnetic orthorhombic phase of barlowite ${\mathrm{Cu}}_{4}{(\mathrm{OD})}_{6}\mathrm{FBr}$ consisting of a layered kagome structure. The divergent behavior of the longitudinal $^{79}(1/{T}_{1})$ and transverse $^{79}(1/{T}_{2})$ relaxation rates observed at $^{79}\mathrm{Br}$ sites evidences that critical slowing down of Cu spin fluctuations sets in below $\ensuremath{\sim}20$ K. This means that one or more Cu sites, most likely at the interlayer Cu(3,4,5) sites between the kagome planes, undergo the antiferromagnetic phase transition in a fairly conventional way. On the other hand, the $^{63}\mathrm{Cu}$ NQR signal intensity is gradually wiped out below $\ensuremath{\sim}30$ K, pointing toward gradual spin freezing of the kagome layers instead. These contrasting findings suggest significant roles played by magnetic frustration effects within the kagome layers.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".