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Record W4392294186 · doi:10.13005/ojc/400124

Chiral ionic Liquid-based Vortex-assisted Enantio-separation of S-(+) and R-(-) Besifloxacin and Evaluation of Zeropoint Energy by Two-phase Liquid-liquid Extraction

2024· article· en· W4392294186 on OpenAlexaff
Eegala Bheema Shankar, Challa Gangu Naidu, S. Devaraju, K.V. Sambasiva Rao, Bondigalla Ramachandra, Srinivasa Rao Yarguntla, Satwinder Singh Marok

Bibliographic record

VenueOriental Journal Of Chemistry · 2024
Typearticle
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsApotex (Canada)
Fundersnot available
KeywordsIonic liquidElsevier BiobaseMaterial chemistryChemistryIndustrial chemistryGreen chemistryFLUIDEXExtraction (chemistry)Supramolecular chemistryFood chemistryLiquid–liquid extractionVortexLiquid liquidPhase (matter)Theoretical chemistryChromatographyOrganic chemistryCatalysisThermodynamicsPhysicsBiochemical engineering

Abstract

fetched live from OpenAlex

Besifloxacin is a fourth-generation fluoroquinolone and shows significant antibacterial properties, which works well against a range of bacteria. Besifloxacin ophthalmic solution is the name of the specific form of this medication used to treat eye infections. The vortex-assisted chiral ionic liquid method was used for the separation of Besifloxacin isomers. S- Besifloxacin shows antibacterial action in clinical trials. The R-isomer, however, has not shown biological properties in clinical testing through different cell line. The current proposed chiral assay method was developed between a racemic mixture and a chiral selector. The analytical databases affirm that 1, 2 dichloroethane is used as a non-aqueous (organic media) solvent and that 1,3-butyl-3-methylimidazole L-tryptophan ([Bmim] [Ltrp]) opted used as a specific chiral ionic liquid. The developed ionic liquid based chital hplc method was successfully applied to separation and purification of isomers of Besifloxacin in during the process industries in bulk drugs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.322
Teacher spread0.309 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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