Ground-state energy of H<sup>−</sup>: a critical test of triple basis sets
Bibliographic record
Abstract
We report an improved variational upper bound for the ground state energy of H − using Hylleraas-like wave functions in the form of a triple basis set having three distinct distance scales. The extended precision DQFUN of Bailey, allowing for 70 decimal digit arithmetic, is implemented to retain sufficient precision. Our result exceeds the previous record [A. M. Frolov, Euro. J. Phys. D 69, 132 (2015)], indicating that the Hylleraas triple basis set exhibits comparable convergence to the widely used pseudorandom all-exponential basis sets, but the numerical stability against roundoff error is much better. It is argued that the three distance scales have a clear physical interpretation. The new variational bound for infinite nuclear mass is –0.527 751 016 544 377 196 590 814 478 a.u. New variational bounds are also presented for the finite mass cases of the hydrogen, deuterium, and tritium negative ions H − , D − , and T − .
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".