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Record W4392579104 · doi:10.5194/egusphere-egu24-10197

A coupled discrete-continuum approach to simulating CO2 migration and dissolution in porous media 

2024· preprint· en· W4392579104 on OpenAlexaff
Nicholas A. Ashmore, Ian L. Molnar, Stuart Gilfillan, M. Król

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsYork University
FundersEngineering and Physical Sciences Research Council
KeywordsPorous mediumDissolutionPorosityPhysicsMechanicsMaterials scienceTheoretical physicsChemical engineeringEngineeringComposite material

Abstract

fetched live from OpenAlex

Carbon capture and storage (CCS) has emerged as a principal emissions reduction technology for the energy transition. Its effectiveness hinges largely on the security of the storage reservoir, which may be susceptible to leakage through permeable pathways such as abandoned wells and faults. Storage failure presents risks of environmental impacts, increases in atmospheric carbon emissions, reduces both the value of carbon credits and public confidence in CCS as a viable technology for the energy transition. Given the importance of storage security, our understanding of CO2 leakage and its fate and transport in overburden must be improved to help in the prediction, detection and assessment of leaks. Shallow groundwater monitoring for dissolved gases can be complicated by multicomponent mass transfer dynamics in the subsurface. As CO2 migrates through the subsurface, much of the mass will partition from the gaseous to the aqueous phase, and conversely background dissolved gases present in groundwater such as N2 and O2 may partition to the gaseous phase, impacting both the evolution of dissolved gas concentrations and the persistence of free-phase gas in the subsurface. This process may also impact the performance of noble gas tracers in groundwater monitoring techniques. There is therefore a need for numerical models capable of accurately predicting the fate and transport of CO2 in the subsurface. However, traditional multiphase flow models struggle to describe the buoyant unstable gas flow regime expected at leak sites, dominated by gravity and capillary forces.Unstable gas flow is characterized by discontinuous gas clusters and sharp variations in gas saturations in space, in contrast with the smooth variation in gas saturation predicted by continuum multiphase flow models. Discrete approaches such as macroscopic invasion percolation (MIP) are better equipped to model unstable gas flow, however they are limited by assumptions of instantaneous gas movement. ET-MIP (Electro-thermal MIP) is a general purpose model which couples continuum-based electrical, thermal, groundwater and chemical species modules with a discrete MIP gas flow module. This coupled approach allows for accurate simulation of slow gas displacement characteristic of shallow subsurface gas releases while simultaneously predicting the dissolution of CO2. ET-MIP has been validated against bench scale experiments and shown to accurately predict gas generation, multiphase transport and capillary trapping – all mechanisms which govern the fate of CO2 in the subsurface. This talk will present comparison of ET-MIP with a bench-scale CO2 injection and dissolution experiment and a sensitivity study showing the effects of key model parameters on CO2 migration. Findings highlight the benefits of using a discrete-continuum coupled approach for simulating CO2 migration in porous media, and the importance of considering background dissolved gases in the subsurface.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.040
Threshold uncertainty score0.080

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0020.001
Open science0.0020.001
Research integrity0.0030.001
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.283
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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