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Record W4392623970 · doi:10.5194/egusphere-egu24-15569

The anaerobic soil volume as a controlling factor of denitrification 

2024· preprint· en· W4392623970 on OpenAlexaff
Steffen Schlüter, Maik Lucas, Balázs Grosz, Olaf Ippisch, Jan Zawallich, Hongxing He, René Dechow, David Kraus, Sergey Blagodatsky, Mehmet Senbeyram, Alexandra Kravchenko, Hans J. Vogel, Reinhard Well

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicWater Resources and Management
Canadian institutionsMcGill University
Fundersnot available
KeywordsDenitrificationAnaerobic exerciseVolume (thermodynamics)ChemistryEnvironmental scienceEnvironmental chemistryThermodynamicsPhysicsBiologyNitrogenPhysiologyOrganic chemistry

Abstract

fetched live from OpenAlex

Denitrification is a major component of the nitrogen cycle in soil that returns reactive nitrogen to the atmosphere. Denitrification activity is often concentrated spatially in anoxic microsites and temporally in ephemeral events, which presents a challenge for modelling. The anaerobic fraction of soil volume can be a useful predictor of denitrification in soils. Here, we provide a review of this soil characteristic, its controlling factors and its estimation from basic soil properties.The concept of the anaerobic soil volume and its link to denitrification activity has undergone several paradigm shifts that came along with the advent of new oxygen and microstructure mapping techniques. The current understanding is that hotspots of denitrification activity are partially decoupled from air distances in the wet soil matrix and are mainly associated with particulate organic matter (POM) in the form of fresh plant residues or manure. POM fragments harbor large amounts of labile carbon that fuels local oxygen consumption and, as a result, these microsites differ in their aeration status from the surrounding soil matrix.Current denitrification models link the anaerobic soil volume fraction to bulk oxygen concentration in different ways but take almost no account of microstructure information, such as the distance between POM and air-filled pores. Based on meta-analyses, we derive new empirical relationships to estimate conditions for the formation of anoxia at the microscale from basic soil properties and we outline how these empirical relationships could be used in the future to improve prediction accuracy of denitrification models at the soil profile scale.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.013
Threshold uncertainty score0.025

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.002
Science and technology studies0.0000.000
Scholarly communication0.0020.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.236
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2024
Admission routes1
Has abstractyes

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