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Record W4392844920 · doi:10.1016/j.lithos.2024.107578

Olivine in ultramafic rocks from the Polaris Alaskan-type intrusion: A geochemical record of open-system crystallization, diffusional re-equilibration, mantle source, and redox conditions in primitive arc magmas

2024· article· en· W4392844920 on OpenAlexafffund
Dylan W. Spence, James S. Scoates, Dejan Milidragovic, J. A. Nott, Graham T. Nixon

Bibliographic record

VenueLithos · 2024
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsGovernment of British ColumbiaGeological Survey of CanadaNatural Resources CanadaUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsOlivineGeologyUltramafic rockFractional crystallization (geology)GeochemistryMelt inclusionsChromiteIgneous differentiationLayered intrusionMantle (geology)Primitive mantleForsteriteAugiteCrystallizationMineral redox bufferMaficMineralogyPartial meltingQuartzThermodynamics

Abstract

fetched live from OpenAlex

Olivine in cumulates from the Early Jurassic Polaris Alaskan-type ultramafic-mafic intrusion in the North American Cordillera displays a wide range of textures and compositions produced in a dynamic crystallization environment as part of a transcrustal arc magmatic system. Major, minor, and trace element analyses of olivine were determined using combined electron probe microanalysis (EPMA) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) to assess the utility of olivine as a petrogenetic indicator in ultramafic intrusions. High forsterite contents (>Fo87) of olivine from dunite, olivine wehrlite, and wehrlite indicate that the parent melts were primitive in composition and that they may represent intrusive analogues to extrusive arc picrites found elsewhere in the Cordillera. Forsterite-Ni systematics (Fo92–80, Ni = 3000–300 ppm) show fractional crystallization-controlled evolution from dunite to olivine wehrlite to wehrlite through olivine clinopyroxenite. Low-Ni olivine (Fo84–80, 500–300 ppm) in magnetite-olivine clinopyroxenite indicates the effects of sulfide melt saturation and Ni-depletion of the residual magma. Entrainment of high-Fo olivine in evolved melts and mixing between fractionated and primitive magmas explains olivine compositions with Ni concentrations (1000–3000 ppm) in excess of those predicted by fractional crystallization models. Extensive subsolidus diffusion of Mg, Fe, Ni, Mn, Ca, Cr, Al, and Li occurred during crystallization and cooling of olivine. Uniform concentrations of Mg, Fe, Ni, and Mn in individual samples and across crystals of olivine indicate complete equilibration in the consolidating cumulate pile. Calcium, Cr, and Al from Polaris olivine (e.g., typically <1000 ppm Ca, <100 ppm Cr and Al), and from plutonic olivine in general, are depleted relative to volcanic olivine as the result of diffusional re-equilibration with interstitial melt and other co-crystallizing phases (Cr-spinel, clinopyroxene). Ratios of first-row transition elements (Mn, Zn, Fe, Co, Ni) in olivine were modified during intracrustal processes (e.g., fractional crystallization, diffusion), however, ratios from the most primitive olivine are indicative of primary mantle signals. Lithium concentrations in olivine (2–12 ppm) show evidence for subsolidus diffusive re-equlibration with Li-enriched melts. Ratios of V/Sc (0.03–0.5) are consistent with relatively oxidized parent magmas and arc mantle sources to Polaris and Alaskan-type intrusions. The Polaris parent magmas ascended through the uppermost mantle and lowermost crust on sufficiently short timescales to avoid significant magmatic differentiation prior to emplacement at a depth of ≤15 km. The findings of this microanalytical study highlight the utility of olivine as a petrogenetic recorder of primary magmatic and high-temperature diffusional processes in ultramafic plutonic rocks and contribute to our understanding of the evolution of primitive arc magmas.

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How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.034
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.220
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes2
Has abstractyes

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