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Record W4392913370 · doi:10.5539/ijc.v16n1p78

Buswell’s Equation for Quantifying Biohydrogen

2024· article· en· W4392913370 on OpenAlexvenueno aff
Pong Kau Yuen, Cheng Man Diana Lau

Bibliographic record

VenueInternational Journal of Chemistry · 2024
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Thermodynamics and Statistical Mechanics
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryBiohydrogenOrganic chemistryHydrogen

Abstract

fetched live from OpenAlex

Biohydrogen is widely generated by dark fermentation and two-stage anaerobic digestion. Anaerobic digestion can be chemically represented by the Buswell’s equation, which is based on elemental composition of organic matter. When compared to Buswell’s equation for biomethane, its equation for biohydrogen has been given less attention. In this article, the nature of Buswell’s equation for biohydrogen is introduced by using the H-atom method. The mean oxidation number of organic carbons is employed as a metric for counting theoretical quantity of biohydrogen and parameters of Buswell’s equation for biohydrogen. Based on an empirical formula and mean oxidation number of organic carbons, the general Buswell’s equation for biohydrogen is developed. The mathematical relationships among mean oxidation number of organic carbons, empirical formula, quantity of biohydrogen, theoretical biohydrogen potential, and biohydrogen percent yield are also established. Biowastes and bio-substrates are chosen to demonstrate this notion.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.952
Threshold uncertainty score0.255

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.335
Teacher spread0.307 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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