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Quantitative Characterization of Partitioning Stringency in SELEX

2024· preprint· en· W4393276834 on OpenAlexafffund
An Le, Eden Teclemichael, Svetlana M. Krylova, Sergey N. Krylov

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicAdvanced biosensing and bioanalysis techniques
Canadian institutionsYork University
FundersNatural Sciences and Engineering Research Council of CanadaYork University
KeywordsSystematic evolution of ligands by exponential enrichmentAptamerMeasure (data warehouse)BiologyInfluencer marketingComputational biologyComputer scienceGeneticsData miningEconomicsGeneRNA

Abstract

fetched live from OpenAlex

Maintaining stringent conditions in SELEX (Systematic Evolution of Ligands by EXponential enrichment) is crucial for obtaining high-affinity aptamers; however, excessive stringency greatly increases the risk of SELEX failure. The control of stringency remains a technical challenge reliant solely on intuition, largely due to the absence of a measure of stringency. Essentially, researchers increase or decrease stringency through its influencers without defining and quantitating it. This study was motivated by our insight that while stringency may not be easily definable via its multiple influencers, it can be delineated by its effect: increasing stringency leads to a decrease in the normalized quantity of binders at the output of partitioning. Building on this insight, we introduce a measure of stringency called the Binder-to-Nonbinder Ratio (BNR) and derive an expression for its experimental determination using a single experimental tool: quantitative PCR. The outcomes of our theoretical analysis and the result of SELEX experiments targeting three distinct protein targets underscore the importance of maintaining a BNR significantly greater than zero to avoid SELEX failure due to excessive stringency – a principle that we term the SELEX non-failure criterion. Utilizing BNR as a measure of stringency alongside this criterion will enable researchers to rationally control SELEX progress.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.006
metaresearch head score (Gemma)0.016
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.006
Threshold uncertainty score0.030

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0060.016
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.002
Scholarly communication0.0020.002
Open science0.0010.002
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.306
Teacher spread0.286 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes2
Has abstractyes

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