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Record W4394679663 · doi:10.1002/ange.202401208

Assembly‐Induced Dynamic Structural Color in a Host‐Guest System for Time‐Dependent Anticounterfeiting and Double‐Lock Encryption

2024· article· en· W4394679663 on OpenAlexaff
Yufan Ji, Tianfu Song, Haifeng Yu

Bibliographic record

VenueAngewandte Chemie · 2024
Typearticle
Languageen
FieldEngineering
TopicModular Robots and Swarm Intelligence
Canadian institutionsMinistry of Education and Child Care
Fundersnot available
KeywordsLock (firearm)ChemistryEncryptionNanotechnologyMaterials scienceComputer scienceComputer networkEngineering

Abstract

fetched live from OpenAlex

Abstract Manipulation of periodic micro/nanostructures in polymer film is of great importance for academics and industrial applications in anticounterfeiting. However, with the increasing demand on information security, materials with time‐dependent features are urgently required, especially the material where the same information can appear more than once on the time scale. Here, one concise strategy to realize time‐dependent anticounterfeiting and “double‐lock” information encryption based on a host‐guest system is proposed, with one photoresponsive azopolymer as the host and one liquid‐crystalline molecule as the guest. The system exhibits a tunable mass transport in pre‐designed periodic micro/nanostructures by tailoring the process of cis‐to‐trans recovery of azo groups and assembly of mesogenic trans‐isomers, resulting in a dynamic structural color in film. Taking advantage of this extraordinary feature, time‐dependent dynamic anticounterfeiting has been achieved. More importantly, the time of each state's appearance in the whole process can be modulated by changing the host‐guest ratio. Combining the manipulatable process of mass transport with the unique decoding method, the stored information in film can be decrypted correctly. This work provides an unprecedented dynamic approach for advanced anticounterfeiting technology with a higher level of security and high‐end applications in information encryption.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.253
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes1
Has abstractyes

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