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Record W4395007089 · doi:10.1007/978-3-031-22926-8_3

Covalent Bonding Theories

2024· book-chapter· en· W4395007089 on OpenAlexaff
R. B. Jordan

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldChemistry
TopicClick Chemistry and Applications
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsCovalent bondChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Aspects of covalent and ionic bonding are discussed. Common terms, such as valence, oxidation state, and formal charge, are defined; the rules for determination of oxidation states are given. The electron dot theory of Lewis and its applications and problems are described. The shapes of species predicted by valence shell electron pair repulsion theory and the ligand close packing model are discussed. Valence bond theory is introduced in its classical or Pauling version and its modern, more quantitative approach. The development of molecular orbital theory and its application to diatomic, triatomic, and hypervalent species are described. The bonding in methane is developed in terms of both theories. The coverage of these topics includes references published through to mid-2021.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.047
Threshold uncertainty score0.158

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.002
Science and technology studies0.0020.003
Scholarly communication0.0030.005
Open science0.0020.002
Research integrity0.0020.002
Insufficient payload (model declined to judge)0.0470.011

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.259
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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