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Record W4395448065 · doi:10.1021/acssuschemeng.4c01669

Lignosulfonates Enable the Coproduction of Fibrillated Lignocellulose and Fermentable Sugars from Chemi-Thermomechanical Wood Fibers

2024· article· en· W4395448065 on OpenAlexafffund
Peipei Wang, Junlong Song, Jie Wu, Yi Lu, Xuetong Shi, Jack Saddler, Orlando J. Rojas, Ran Bi

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2024
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Cellulose Research Studies
Canadian institutionsUniversity of British Columbia
FundersGraduate Research and Innovation Projects of Jiangsu ProvinceChina Scholarship CouncilCanada Excellence Research Chairs, Government of CanadaCanada Foundation for Innovation
KeywordsLignosulfonatesLigninCellulaseCellulosePulp and paper industryMaterials scienceChemical engineeringBioconversionHydrolysisEnzymatic hydrolysisChemistryPulp (tooth)SugarComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

Lignosulfonates (LS) are known to reduce the recalcitrance of wood fibers to enzymatic hydrolysis. This study furthers the use of LS for the bioconversion of chemi-thermomechanical pulp (CTMP, ca. 26% lignin) at high solids content (10%) using a cellulase and hemicellulase prehydrolysis complex combined with LS loading (dual treatment). The process (10% solids, 12 h) increases the sugar yield by 20% and produces high-quality lignin-containing cellulose nanofibrils (LCNF) by mechanical fibrillation. Moreover, the dual treatment yields nanofibrils of smaller lateral size and enables better colloidal stability compared with those obtained by enzyme treatment alone or by sequential application (LS addition after enzyme). Translucent films were produced with LCNF, which are shown for their reduced hydrophilicity, high mechanical strength, and UV shielding performance. The introduced approach for efficient utilization of lignocellulose resources to coproduce high-value fibrillated lignocellulose and sugars is expected to lead to new opportunities given the availability of CTMP under the persistent reduction in demand of newsprint and printing grades.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.213
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2024
Admission routes2
Has abstractyes

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Same venueACS Sustainable Chemistry & EngineeringSame topicAdvanced Cellulose Research StudiesFrench-language works237,207