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Record W4396213863 · doi:10.1021/acsami.4c00415

Melamine Network as a Solution for Significant Enhancement of the Mechanical, Adsorptive, and Surface Properties in a Novel Carbon Nanomaterial–Silica Aerogel Composite

2024· article· en· W4396213863 on OpenAlexafffund
Maryam Fashandi, Zeineb Ben Rejeb, Hani E. Naguib, Chul B. Park

Bibliographic record

VenueACS Applied Materials & Interfaces · 2024
Typearticle
Languageen
FieldChemistry
TopicAerogels and thermal insulation
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceAerogelMelamineComposite numberNanomaterialsCarbon fibersSurface modificationComposite materialAdsorptionActivated carbonChemical engineeringNanotechnologyOrganic chemistry

Abstract

fetched live from OpenAlex

Silica aerogels exhibit exceptional characteristics such as mesoporosity, light weight, high surface area, and pore volume. Nevertheless, their utilization in industrial settings remains constrained due to their brittleness, moisture sensitivity, and costly synthesis procedure. Several studies have proved that adding nanofillers, such as carbon nanotubes (CNT) or graphene nanoplatelets (GNP), can improve the mechanical strength of the aerogels. The incorporation of nanofillers is often accompanied by agglomeration and pore blockage, which, in turn, deteriorates the surface area, pore volume, and low density. Including flexible melamine foam (MF) as a scaffold for the silica aerogel and nanofiller composite can prevent the restacking of the nanofillers through π–π interaction, hence maintaining the incredible properties of aerogels and improving their mechanical properties. CNT, GNP, and the polymeric silica precursor, polyvinyltrimethoxysilane (PVTMS), were added to a MF, at varying concentrations, to fabricate the MF-aerogel nanocomposites. Surfactant and sonication were utilized to ensure a homogeneous dispersion of the nanofillers in the system. The presence of MF prevented the agglomeration of nanofillers, resulting in lower density and relatively higher surface properties ( S BET up to 929 m 2 ·g –1 and pore volume up to 4.34 cc·g –1 ). Moreover, the MF-supported samples could endure 80% strain without breakage and showed an outstanding compressive strength of up to ∼20 MPa. These aerogel nanocomposites also demonstrated an excellent volatile organic compound (∼2680 mg·g –1 ) and cationic dye adsorption (∼10 mg·g –1 ).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.622

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.229
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2024
Admission routes2
Has abstractyes

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