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Record W4396228345 · doi:10.1002/cjce.25281

Simulation study of the electrothermal field in a chloride electrolysis cell with 16 electrode pairs

2024· article· en· W4396228345 on OpenAlexvenueno aff
Qian Liu, Taixi Feng, Shigui Zhu, Guimin Lu

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicMolten salt chemistry and electrochemical processes
Canadian institutionsnot available
FundersNational Natural Science Foundation of China
KeywordsElectrolysisAnodeElectrolyteElectrolytic processElectrolytic cellElectrodeMaterials scienceThermalCurrent (fluid)MechanicsChemistryNuclear engineeringThermodynamicsPhysicsEngineering

Abstract

fetched live from OpenAlex

Abstract The spatial distribution of the electrothermal field within molten salt electrolytic cells significantly influences the efficiency of the electrolysis process, the quality of the end products, and the overall stability of the system. Enhancing the design of chloride electrolysis cells can lead to marked improvements in both process efficiency and system stability, thereby yielding increased economic benefits. This study introduces a design for a chloride electrolysis cell and examines the thermal budget under elevated electrical current intensities across 16 electrode pairs. It further analyzes the degree to which various parameters affect thermal equilibrium. The findings indicate that the electrolytic cell maintains a small thermal budget discrepancy at a current intensity of 124 kA and is less than 5%, with substantial heat dissipation observed at the surface of the top area of anode exposure and considerable energy consumption at both the anode and the electrolyte. Dimensionless treatment of the different parameterized simulation results has been conducted to develop a nondimensional equation, describing the thermal equilibrium conditions within the electrolytic cell. This foundational work paves the way for further investigations into the interactions between the electrothermal field and other physical fields, as well as for the optimization of the electrolytic cell's geometry and design.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score0.036

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.188
Teacher spread0.184 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes1
Has abstractyes

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Same venueThe Canadian Journal of Chemical EngineeringSame topicMolten salt chemistry and electrochemical processesFrench-language works237,207