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Multiparameter optimization of microbial fuel cell outputs using linear sweep voltammetry and microfluidics

2024· article· en· W4396242623 on OpenAlexafffund
Jayesh M. Sonawane, Jesse Greener

Bibliographic record

VenueJournal of Power Sources · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicMicrobial Fuel Cells and Bioremediation
Canadian institutionsUniversité Laval
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsLinear sweep voltammetryMicrobial fuel cellMicrofluidicsFuel cellsVoltammetryCyclic voltammetryBiological systemMaterials scienceChemistryComputer scienceBiochemical engineeringAnalytical Chemistry (journal)Process engineeringNanotechnologyChemical engineeringChromatographyEngineeringElectrochemistryElectrodeBiology

Abstract

fetched live from OpenAlex

A microbial fuel cell with a mature pure-culture Geobacter sulfurreducens electroactive biofilm was used for performance optimization by making rapid changes to experimental parameters in microchannels while monitoring their effect using linear sweep voltammetry. A systematic investigation of polarization behavior and evaluation of system resistivity provided important figures of merit and mechanistic insights on the effects of flow rates, concentrations, and temperature. After individual parameters were optimized, a synergistic effect was observed by applying optimal parameters together, resulting in improved current and maximum power densities, compared to stable values at unoptimized conditions. Continued acclimation for just 2 days under these conditions resulted in further improvements to anode area-normalized current and power maxima (10.49 ± 0.23 A m −2 and 2.48 ± 0.27 W m −2 ), which are among the highest reported in the literature for a microfluidic MFC. In keeping with other accepted normalization protocol using the area separating anode and cathode chambers, the output densities were 64 A m −2 and 15 W m −2 , which are near the theoretical maximum outputs achievable with an MFC system. • Operational parameters were rapidly and accurately modified with microfluidic control. • Linear scan voltammetry reported power and current outputs plus internal resistances. • Individual optimized operational parameters were determined. • Optimization reduced internal resistances and delayed mass-transport limitations. • Maximum outputs were 15 W m −2 and 63 W m −2 when normalized by anolyte contact area.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.111
Threshold uncertainty score0.347

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.217
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2024
Admission routes2
Has abstractyes

Explore more

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