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Record W4396945855 · doi:10.1039/d4fd00070f

Ion transport in polymerized ionic liquids: a comparison of polycation and polyanion systems

2024· article· en· W4396945855 on OpenAlexafffund
Javad Jeddi, Jukka Niskanen, Benoît H. Lessard, Joshua Sangoro

Bibliographic record

VenueFaraday Discussions · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicIonic liquids properties and applications
Canadian institutionsUniversity of Ottawa
FundersDivision of Materials ResearchNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsIonPolymerizationIonic bondingIonic liquidChemical physicsChemistryIon transporterScatteringInorganic chemistryPolymerOrganic chemistryOpticsPhysicsCatalysis

Abstract

fetched live from OpenAlex

, the decoupling index, often used to quantify the extent to which segmental dynamics and ion conduction are correlated, remains unaltered for the polyILs studied, suggesting that this index may not be a general parameter to characterize charge transport in polymerized ionic liquids. Furthermore, detailed analyses of the WAXS results indicate that both the mobile ion type and the structure of the pendant groups control mesoscale organization. These findings are discussed within the framework of recent models, which account for the subtle interplay between electrostatic and elastic forces in determining ion transport in polyILs. The findings demonstrate the intricate balance between the chemical structure and interactions in polyILs that determine ion conduction in this class of polymer electrolytes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.801
Threshold uncertainty score0.368

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.276
Teacher spread0.260 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2024
Admission routes2
Has abstractyes

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