Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers
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Bibliographic record
Abstract
High Resolution Image Download MS PowerPoint Slide Three pentaborates were made by precise structural regulations under hydrothermal conditions, namely, K 2 Cs[B 5 O 8 (OH)]·0.5CO 3 ( 1 ), KNa 4 Cs[B 5 O 8 (OH)] 2 ·2OH ( 2 ), and NaBa[B 5 O 8.5 (OH)] ( 3 ). Compound 1 features the typical 2D layers constructed from the four-connected B 5 O 10 (OH) clusters. By adjustment of the reactants and pH values of the systems to remove interlayered CO 3 2– groups, the centric layers in 1 were transformed to the chiral layers of 2 . By further adjusting cationic templates based on host–guest charge matching, the B 5 O 10 (OH) cluster unit was transformed to B 5 O 11 (OH), which built the chiral porous layers of 3 . The chiral compounds 2 and 3 exhibit moderate second harmonic generation (SHG) responses of 1.1 and 1.7 times that of KDP (KH 2 PO 4 ). The structural regulations actualize the evolutions on both structural symmetries and dimensions.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it