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Record W4399586158 · doi:10.1089/ees.2024.0017

Microplastic Mass Quantification Using Focal Plane Array-Based Micro-Fourier-Transform Infrared Imaging

2024· article· en· W4399586158 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnvironmental Engineering Science · 2024
Typearticle
Languageen
FieldEnvironmental Science
TopicMicroplastics and Plastic Pollution
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsInfraredFourier transformCardinal pointFourier transform infrared spectroscopyMaterials scienceOpticsMass spectrometryChemical imagingFocal Plane ArraysMass spectrometry imagingHyperspectral imagingRemote sensingPhysicsChemistryChromatographyGeology

Abstract

fetched live from OpenAlex

The quantification of microplastics (MPs) in environmental samples on a mass basis can be used to provide a more comprehensive understanding of the fate and transport of MPs in the environment. In this study, a precise method for quantifying the volumes and, by extension, the masses of MPs was developed. This novel approach is grounded in the principles of Beer’s law and makes use of focal plane array (FPA) micro-Fourier-transform infrared imaging. This methodology capitalizes on the absorption characteristics observed at each pixel within FPA imaging data, to identify variations in thickness across the x–y plane and facilitate a comprehensive characterization of the 3D geometries of MPs. This approach represents an advancement from previous assumptions that treated all MPs as regularly shaped and extrapolated thickness information solely based on x–y coordinates. Linear regression was used to model the relationship between absorbance and plastic thickness, drawing from data collected from plastic membranes with controlled thickness. The model was validated through a comparison between known and estimated volumes of MPs characterized by well-defined geometries, yielding errors <5%, substantiating the validity and accuracy of the proposed approach. The proposed method developed in this study holds the potential to emerge as a standard protocol for the accurate quantification of MP mass in environmental samples.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.652
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.189
Teacher spread0.183 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it