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Record W4399762567 · doi:10.1139/er-2023-0097

Americium-241 in peat bogs as a global marker of the beginning of the Anthropocene: examples from Europe and North America

2024· article· en· W4399762567 on OpenAlexafffundvenue
Andrii Oleksandrenko, P. G. Appleby, M. John M. Duke, Tommy Noernberg, William Shotyk

Bibliographic record

VenueEnvironmental Reviews · 2024
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsAnthropoceneBogPeatEnvironmental scienceEcologyGeographyBiology

Abstract

fetched live from OpenAlex

Fallout radionuclides are being considered as potential global indicators of the beginning of the Anthropocene, yet questions persist about their preservation in bogs. This study assessed the reliability of 241 Am records in peat cores from acidic, ombrotrophic bogs. The source of 241 Am (half-life 432.7 years) in these natural archives is radioactive decay of the short-lived plutonium isotope 241 Pu (half-life 14.329 years) present in fallout from the atmospheric testing of nuclear weapons. We leveraged previously gathered data to gauge the congruence of 241 Am records with 210 Pb dates, examining the alignment of the 241 Am activity peak with the depth corresponding to the year AD 1963, as determined using the 210 Pb constant rate of supply (CRS) model. Our analysis employed 35 peat cores from 30 sites across Europe and North America, collected over the last three decades for trace metal deposition studies. Each core underwent independent 210 Pb dating. Among the 35 cores, 10 were excluded because of significant uncertainty in 241 Am peak quantification. Among the remaining 25 cores, 22 displayed a single 241 Am peak and 3 exhibited two peaks with similar 241 Am activities. Of the 22 cores with a single peak, 18 were within 10 years of AD 1963, with 10 of those being within 5 years. For 10 of the 22 cores, 14 C dates obtained from the atmospheric bomb pulse curve enabled comparison, with 9 showing ≤10 years of difference and 7 of those showing ≤5 years from the 210 Pb CRS model AD 1963. Factors contributing to age discrepancies included (i) analytical limitations of 241 Am measurements in peat using gamma spectrometry, (ii) the impact of peat accumulation rates on 241 Am activities, i.e., dilution effects, (iii) post-depositional migration of 241 Pu and (or) 241 Am, (iv) uncertainties introduced during 210 Pb age-modelling, and (v) the limited number of samples dated using 14 C. The usefulness of 241 Am as an Anthropocene marker (assuming AD 1963) hinges on the accepted uncertainty level in defining this epoch. Detection of 241 Am through gamma spectrometry was statistically validated as a real peak in 22 out of a total of 35 cores: this fraction (63%) is within the range reported in other studies. Given that the cores were gathered from 16 European and 14 North American sites, these peaks can be taken to denote the hemispheric onset of the Anthropocene. Lastly, common post-depositional migration of 137 Cs in ombrotrophic peatlands contrasts with its immobility in minerotrophic peatlands, where the presence of mineral matter and neutral pH inhibit its movement. This observation suggests that fens and swamps, characterized by minerotrophic conditions, may also serve as repositories of nuclear weapons test fallout, including 241 Am.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.097
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.206
Teacher spread0.196 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes3
Has abstractyes

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