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Record W4399767146 · doi:10.54097/1ab8v510

Application of metal-organic frameworks for CO2 capture

2024· article· en· W4399767146 on OpenAlexaboutno aff
XingKai Zhao

Bibliographic record

VenueHighlights in Science Engineering and Technology · 2024
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsFlue gasAdsorptionMetal-organic frameworkEnvironmentally friendlyCombustionSelectivityCarbon dioxideProduction (economics)FlueYield (engineering)DurabilityProcess engineeringMaterials scienceWaste managementChemistryEngineeringOrganic chemistryMetallurgyComposite materialCatalysis

Abstract

fetched live from OpenAlex

The emission of carbon dioxide (CO2) is gradually increasing, and CO2 adsorption from post-combustion processes in thermal power plants could be a viable option. As a solid adsorbent for CO2 capture, metal-organic frameworks (MOFs) have higher selectivity and capacity for flue gas. Compared with traditional adsorbents, calgary framework 20 (CALF-20) that belongs to a zinc-based MOFs, efficiently captures CO2 from flue gas and is affordable and durable also, which lays the foundation for its large-scale production. This article will introduce the overall idea of CO2 adsorption, the structure of CALF-20, selectivity for N2 and H2O, competitive adsorption with H2O-CO2 and durability, and verify the excellent performance of CALF-20 with experimental results. In addition, the possibility of mass production was also shown. Specifically, CALF-20 is not as difficult to large scaling produce as other MOFs. In fact, its large-scale industrial production is feasible with its advantages of low cost, high yield, stability, environmentally friendly and safety.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.226
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes1
Has abstractyes

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