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Record W4399777758 · doi:10.26434/chemrxiv-2024-jjj4n

Burner system for solid sample flame emission spectroscopy

2024· preprint· en· W4399777758 on OpenAlexafffund
Adam Bernicky, Boyd Davis, Hans‐Peter Loock

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldEngineering
TopicLaser-induced spectroscopy and plasma
Canadian institutionsUniversity of VictoriaQueen's University
FundersNational Research Council CanadaNatural Sciences and Engineering Research Council of Canada
KeywordsCombustorElemental analysisSpectroscopyAnalytical Chemistry (journal)Materials scienceEmission spectrumAcetyleneAtomic emission spectroscopySample (material)Process engineeringChemistrySpectral lineCombustionPlasmaInorganic chemistryChromatographyOrganic chemistryEngineering

Abstract

fetched live from OpenAlex

We present a burner system to analyze solid inflammable samples utilizing flame emission spectroscopy without requiring any sample preparation procedures. The acetylene-nitrous oxide burner was designed to efficiently introduce solid particles into the flame through active injection, enabling real-time elemental analysis. Computational Fluid Dynamics (CFD) simulations were employed to study particle transport dynamics within the burner system. The emission was characterized through spectral analysis of the flame emission from metal powder mixtures, demonstrating its ability to determine elemental compositions without prior sample treatment. An artificial neural network (ANN) was implemented to analyze spectral data obtained from binary metal mixtures, enabling rapid and reliable identification of constituent elements with an uncertainty of = 2.7 % (mol/mol)

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.074
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.262
Teacher spread0.246 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2024
Admission routes2
Has abstractyes

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