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Record W4399828025 · doi:10.32920/26052760

Photoinduced Luminescence Enhancement of Hydrophilic 'Caged' Carbons Dots

2024· preprint· en· W4399828025 on OpenAlexaff
Aviya S. Akari

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldMaterials Science
TopicCarbon and Quantum Dots Applications
Canadian institutionsToronto Metropolitan University
Fundersnot available
KeywordsLuminescencePhotochemistryMaterials scienceNanotechnologyOptoelectronicsChemical engineeringChemistry

Abstract

fetched live from OpenAlex

<p>Over the last decade, carbon dots (CDs) have quickly emerged as outstanding 'green' nanoprobes for fluorescence imaging and microscopy techniques. In this context, the identification of a mechanism to tune the CD's optical properties (e.g., fluorescence) can translate into the development of photoactivatable probes with improved performance for super-resolution bioimaging. In relation to this, facile synthetic protocol was devised to photoactivate the luminescence of two types of hydrophilic carbon dots (-COOH and -N doped carbon dots) by 'caging' the nanostructures with photocleavable 2-nitrobenzyl groups. It was demonstrated that 2nitrobenzyl groups efficiently quench the emission intensity of both resulting nanoconstructs. Nonetheless, the luminescence of the 'caged' carbon dots can be partially recovered, upon ultraviolet illumination, in solution.</p>

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.032
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.002
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.282
Teacher spread0.260 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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