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Record W4400468217 · doi:10.1007/s12598-024-02830-6

Rhenium‐boosted electrocatalytic activity and durability of pyrolytic IrO <sub>2</sub> for acidic oxygen evolution

2024· article· en· W4400468217 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueRare Metals · 2024
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsMinistry of Education and Child Care
FundersNational Natural Science Foundation of China
KeywordsPyrolytic carbonRheniumOxygen evolutionDurabilityChemistryOxygenElectrocatalystInorganic chemistryElectrochemistryMaterials scienceElectrodePyrolysisOrganic chemistryComposite materialPhysical chemistry

Abstract

fetched live from OpenAlex

摘要 IrO 2 以其在酸性介质中的出色稳定性而闻名,但是析氧反应(OER)活性有限。为了在保持其超高稳定性的同时增强本征OER活性,本文报道了一种使用热分解方法合成的掺入杂原子铼(Re)的热解IrO 2 。由此方法合成的Ir 0.928 Re 0.072 O 2 电极在0.5 M H 2 SO 4 溶液中表现出了明显的本征OER活性提高,比原始IrO 2 高出4倍,10 mA·cm ‐2 对应的过电位仅为209 mV。重要的是,Ir 0.928 Re 0.072 O 2 电极可以在200 mA·cm ‐2 的大电流密度下维持400小时以上的酸性OER。这些发现为降低IrO 2 基电催化剂在酸性OER电化学工业领域的能耗带来了巨大的希望。

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.231
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it