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Record W4400586628 · doi:10.1063/5.0218742

Stress relaxation following sudden cessation of steady shearing from polymer rotarance theory

2024· article· en· W4400586628 on OpenAlexfundno aff
Myong Chol Pak, A. Jeffrey Giacomin, M. A. Kanso

Bibliographic record

VenuePhysics of Fluids · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicRheology and Fluid Dynamics Studies
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPhysicsShearing (physics)MechanicsThermodynamicsClassical mechanics

Abstract

fetched live from OpenAlex

Deriving rheological material functions from rotarance theory proceeds in two steps. We first solve the general diffusion equation to get the polymer orientation distribution, then we integrate the result in phase space to get the material functions. Rotarance theory thus relies entirely on polymer orientation to explain the elasticity of a polymeric liquid and, thus, to explain how such complex fluids depart from Newtonian behavior. We are attracted to rotarance theory by virtue of its versatility. The rheological behavior can be deduced, from first principles, from the structure of the macromolecule. However, of the 13 canonical rheological material functions, 5 are still unknown. We devote this paper to stress relaxation following cessation of steady shear flow. We arrive at analytical expressions for the relaxation of the orientation distribution function and then integrate this to get expressions for the relaxation of the shear stress, along with both normal stress differences.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.489
Threshold uncertainty score0.437

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.237
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2024
Admission routes1
Has abstractyes

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